2024/01/21 更新

写真a

キダ タクミツ
木田 拓充
KIDA Takumitsu
所属
先端工学研究院
部局
工学部 ガラス工学研究センター
職名
講師
外部リンク

学歴

  • 金沢大学   理工学域   自然システム学類

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  • 金沢大学   自然科学研究科   自然システム学専攻 博士後期課程

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  • 金沢大学   自然科学研究科   自然システム学専攻 博士前期課程

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学位

  • 博士(工学) ( 2019年3月   金沢大学 )

研究キーワード

  • 高分子物性

  • 高分子化学

  • 力学物性

  • レオロジー

  • ラマン分光法

  • ポリオレフィン

  • ポリエチレン

  • 高分子材料物性、レオロジー、振動分光法、力学試験

▼全件表示

経歴

  • 滋賀県立大学   工学部 ガラス工学研究センター   講師

    2023年4月 - 現在

  • 滋賀県立大学   工学部 材料化学科   講師

    2023年4月 - 現在

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    国名:日本国

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  • 北陸先端科学技術大学院大学   先端科学技術研究科   助教

    2021年4月 - 2023年3月

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    国名:日本国

  • 名古屋大学   大学院工学研究科 物質科学専攻   特任助教

    2021年1月 - 2021年3月

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  • 広島大学   大学院工学研究科   学術振興会特別研究員PD

    2019年4月 - 2020年12月

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  • 金沢大学   自然科学研究科   学術振興会特別研究員DC1

    2016年4月 - 2019年3月

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所属学協会

  • マテリアルライフ学会

    2023年4月 - 現在

  • 高分子分析研究懇談会

    2021年10月 - 現在

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  • プラスチック成形加工学会

    2019年1月 - 現在

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  • 繊維学会

    2016年4月 - 現在

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  • 日本レオロジー学会

    2014年4月 - 現在

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  • 高分子学会

    2013年9月 - 現在

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▼全件表示

研究分野

  • ナノテク・材料 / 高分子化学

  • ナノテク・材料 / 高分子材料

委員歴

  • 日本レオロジー学会   代表委員  

    2021年5月 - 現在   

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    団体区分:学協会

  • 日本レオロジー学会   編集委員  

    2023年5月 - 現在   

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    団体区分:学協会

  • プラスチック成形加工学会   編集委員  

    2022年7月 - 現在   

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  • 高分子分析研究懇談会   運営委員  

    2022年5月 - 現在   

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    団体区分:学協会

  • プラスチック成形加工学会   年次大会運営委員  

    2022年4月 - 現在   

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研究シーズ

  • 不均一構造を利用した 高性能・高機能プラスチックの開発

論文

  • In-situ Raman spectroscopic study of conformational reorganization during heat treatment for high-density polyethylene solid 査読

    Misato Nabata, Takumitsu Kida, Yusuke Hiejima, Koh-hei Nitta

    Polymer   290   126558 - 126558   2024年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier BV  

    DOI: 10.1016/j.polymer.2023.126558

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  • Optimum processing conditions for the maximum crystallization rate of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) 査読

    Janchai K., Kida T., Yamaguchi M., Sunagawa T., Okura T.

    Scientific Reports   13 ( 1 )   2023年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Scientific Reports  

    The effect of thermal and shear histories on the crystallization rate of poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBHHx) was studied. As with other crystalline polymers, the shear history greatly affected the crystallization rate when the shear rate was beyond a critical value, i.e., the inverse of the Rouse relaxation time. Even after the formation of extended chain crystals, spherulite texture was clearly discernable. It grew from certain points on the extended chain crystals. Consequently, a row of spherulites appeared along the flow direction. The resin temperature in the molten state was also significant. When the sample was heated to 170 °C, which is beyond the main melting peak in the differential scanning calorimetry curve, unmolten crystals did not affect the linear viscoelastic properties. They acted as effective nucleating agents for the rest of the polymer during cooling. Therefore, the shear history hardly affected the crystallization rate and the number of spherulites.

    DOI: 10.1038/s41598-023-27595-3

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85146106118&origin=inward

  • Compressive double yielding in high-density polyethylene over a wide range of strain rates 査読

    Yusuke Hiejima, Nobuhiro Misumi, Ryohei Ippitsu, Takumitsu Kida, Masahiro Higuchi, Hiroyuki Yamada, Koh-hei Nitta

    Polymer   291   126590 - 126590   2023年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier BV  

    DOI: 10.1016/j.polymer.2023.126590

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  • Rheological Properties of poly(Lactic acid) Modified by Cellulose Acetate Propionate 査読

    Takeyoshi Kimura, Tomoki Takeuchi, Panitha Phulkerd, Pornchanok Pichaipanich, Daisuke Kugimoto, Shingo Kouda, Takumitsu Kida, Masayuki Yamaguchi

    Journal of Polymers and the Environment   2023年10月

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    掲載種別:研究論文(学術雑誌)   出版者・発行元:Springer Science and Business Media LLC  

    DOI: 10.1007/s10924-023-03104-5

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    その他リンク: https://link.springer.com/article/10.1007/s10924-023-03104-5/fulltext.html

  • Modification of melt memory effect by addition of poly(butylene terephthalate) to thermoplastic polyester elastomer 査読

    Takumi Yamada, Takumitsu Kida, Masayuki Yamaguchi

    Polymer   285   126330 - 126330   2023年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier BV  

    DOI: 10.1016/j.polymer.2023.126330

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  • Morphological transformation of extruded isotactic polypropylene film from the Mesophase to α-form crystals 査読

    Takumitsu Kida, Yuta Fukuda, Masayuki Yamaguchi, Yasuhiko Otsuki, Tokutaro Kimura, Tomoaki Mizukawa, Tomoya Murakami, Kazuki Hato, Tomoya Okawa

    Reactive and Functional Polymers   191   105682 - 105682   2023年10月

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    担当区分:筆頭著者, 責任著者   記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier BV  

    DOI: 10.1016/j.reactfunctpolym.2023.105682

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  • Mechanical properties of isotactic polypropylene with nodular or spherulite morphologies 査読

    Yuta Fukuda, Takumitsu Kida, Masayuki Yamaguchi

    Polymer Engineering & Science   2023年9月

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    担当区分:責任著者   記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Wiley  

    Abstract

    α‐form crystalline isotactic polypropylene (PP) was prepared by two methods: quenching from the melt state at slow or high crystallization rates. The mechanical properties of the resulting PP samples were evaluated using tensile and stress–relaxation tests to investigate the influence of nodular or spherulite morphologies. PP samples with different morphologies had almost the same crystallinity after annealing at 100°C for 5 h. The yielding stress, strain‐hardening modulus, and strength of the nodular PP were higher than those of the spherulite PP, although the crystallinity was almost the same for both PP samples. Furthermore, the relaxation time during the stress–relaxation process at ε = 4.0 was longer for the nodular PP than for the spherulite PP. The lamellar structure of a spherulite morphology comprises parent and daughter lamellar crystals, whereas that of a nodular morphology prepared via a mesophase structure comprises only parent lamellar crystals. The formation of the daughter lamellae reduces the number of tie chains. Therefore, the nodular PP has more tie chains than the spherulite PP. This transformation from a spherulite to a nodular morphology improved the mechanical properties of the PP.

    Highlights

    Influences of morphology on mechanical properties of polypropylene (PP).

    Tensile properties were higher for nodular PP than spherulite PP.

    Relaxation time of nodular PP was longer than spherulite PP.

    Nodular PP has more tie chains, resulting in improvements of tensile properties.

    DOI: 10.1002/pen.26504

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  • Enhancing the Mechanical Properties of Poly(vinyl alcohol) Fibers by Lithium Iodide Addition 査読

    Yusuke Taoka, Riza Asmaa Saari, Takumitsu Kida, Masayuki Yamaguchi, Kazuaki Matsumura

    ACS Omega   8 ( 36 )   32623 - 32634   2023年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:American Chemical Society (ACS)  

    DOI: 10.1021/acsomega.3c03280

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  • Flow-induced crystallization behavior of high-density polyethylene evaluated by Rheo-Raman spectroscopic system 査読

    Takumitsu Kida, Khunanya Janchai, Katsuhisa Tokumitsu, Masayuki Yamaguchi

    Polymer Journal   2023年7月

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    担当区分:筆頭著者, 責任著者   記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Springer Science and Business Media LLC  

    DOI: 10.1038/s41428-023-00821-5

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    その他リンク: https://www.nature.com/articles/s41428-023-00821-5

  • Viscoelastic properties of copolycarbonates comprising isosorbide and 1,4-cyclohexanedimethanol 査読

    Ruiqi Han, Takumitsu Kida, Masayuki Yamaguchi

    Colloid and Polymer Science   2023年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Springer Science and Business Media LLC  

    DOI: 10.1007/s00396-023-05143-9

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    その他リンク: https://link.springer.com/article/10.1007/s00396-023-05143-9/fulltext.html

  • Anomalous Postprocessing Dimensional Change of Injection-Molded Products Composed of Poly(lactic acid) and Poly(vinyl alcohol) 査読

    Yamaguchi M., Shu W., Kimura T., Vo H.G.D., Kida T., Mori T., Kitani M., Aridome N., Miyamoto A.

    ACS Applied Polymer Materials   5 ( 3 )   2136 - 2143   2023年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ACS Applied Polymer Materials  

    The present study revealed that an injection-molded product comprising poly(lactic acid) (PLA) and poly(vinyl alcohol) (PVAL) exhibited an anomalous dimensional change, i.e., expansion in the flow direction, after postprocessing annealing (around 2.9% expansion by annealing at 80-100 °C for 3 h). Although the crystallization of the PLA during cooling was not accelerated by the addition of PVAL, the PLA showed transcrystallization from the dispersed PVAL droplets, which were deformed in the flow direction, during postprocessing annealing. Therefore, after annealing, the injection-molded products exhibited a high degree of molecular orientation, in contrast to the original unannealed products, which were not oriented. This anomalous behavior should be noted as a means of controlling dimensional change after processing.

    DOI: 10.1021/acsapm.2c02155

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    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85149045515&origin=inward

  • Role of Shear Flow on Structure Development during Post-Processing Annealing for Poly(lactic acid) 査読

    Vo H.G.D., Kida T., Yamaguchi M.

    Polymers   15 ( 3 )   2023年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Polymers  

    The effect of shear history on structure development during post-processing annealing was studied using poly(lactic acid) PLA. Since PLA shows a low crystallization rate, quenched films had no crystallinity. Moreover, molecular orientation was not detected in the films. During the annealing procedure beyond its glass transition temperature, however, molecular orientation to the flow direction occurred with the crystallization growth in the films having an appropriate shear history. This peculiar crystal growth during the annealing was most probably attributed to the crystallization from extended chain crystals generated during the applied shear history, although the amount of extended chain crystals was low. The results obtained in this study should be noted because the molecular orientation proceeded due to the annealing history applied. Furthermore, this phenomenon will be used to suppress dimensional change and increase product rigidity.

    DOI: 10.3390/polym15030693

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    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85148000207&origin=inward

  • Preparation of graded materials for miscible polycarbonate/poly(methyl methacrylate) blends by segregation under shear flow 査読

    Moonprasith N., Tatsumichi M., Nakamura K., Kida T., Tsubouchi K., Hiraoka T., Yamaguchi M.

    Journal of Applied Polymer Science   140 ( 1 )   2023年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Journal of Applied Polymer Science  

    Exposure to shear flow produced by a pressure-driven capillary rheometer provides a concentration gradient without phase separation in miscible polymer blends of bisphenol-A polycarbonate containing low-molecular-weight poly(methyl methacrylate) (PMMA). The strand surface extruded from the rheometer contains a large amount of PMMA. However, the strand is transparent because there is no light scattering due to phase separation. The segregation behavior, that is, enrichment of the PMMA content at the strand surface, is enhanced when the molecular weight of PMMA is low. Furthermore, the segregation is also enhanced at high temperatures and at high shear rates. By contrast, the die length barely affects the degree of segregation. The segregation phenomenon should be noted because it may facilitate the modification of the surface properties of various products.

    DOI: 10.1002/app.53258

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85140109307&origin=inward

  • Improvement in Processability for Injection Molding of Bisphenol-A Polycarbonate by Addition of Low-Density Polyethylene 査読

    Kuroda Y., Suzuki K.I., Kikuchi G., Moonprasith N., Kida T., Yamaguchi M.

    Materials   16 ( 2 )   2023年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Materials  

    The rheological properties and processability at injection molding were studied for bisphenol-A polycarbonate (PC) that was modified by low-density polyethylene (LDPE) having a low shear viscosity. The LDPE addition significantly decreased the steady-state shear viscosity, especially in the high shear rate region. The decrease did not originate from slippage on the die wall but due to interfacial slippage between the PC and dispersed LDPE droplets that deformed to the flow direction to a great extent. As a result of the viscosity decrease, injection pressure largely decreased from 150 to 110 MPa with the addition only 5 wt.% of LDPE. The enhanced flowability also reduced the warpage of the molded product significantly, demonstrating that the processability at injection molding was improved by the addition of LDPE.

    DOI: 10.3390/ma16020866

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    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85146422095&origin=inward

  • Direct Observation of the Effect of a High-Molecular-Weight Component on the Deformation Behavior of Polyethylene Solids Using the Rheo-Raman Spectroscopic Technique 査読

    Kida T., Tanaka R., Shiono T., Yamaguchi M.

    Macromolecules   2023年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Macromolecules  

    We investigated the effects of molecular components of different molecular weights on the tensile properties of polyethylene (PE) by measuring the microscopic deformation of deuterated molecular chains of various molecular weights and narrow molecular weight distributions using rheo-Raman spectroscopy. The strain-hardening modulus increased by adding the high-molecular-weight chains connecting more than four to six lamellar crystalline layers. These high-molecular-weight molecular chains showed large peak shifts and orientation parameter values during strain hardening. In contrast, almost no stretching load was applied to the low-molecular-weight molecular chains that connected only two or three lamellar crystals in the strain-hardening region, and the strain-hardening modulus was unchanged by adding these low-molecular-weight chains. These results suggest that the high-molecular-weight molecular chains connecting more than four to six lamellar crystals act as stress transmitters throughout the crystal structure in the strain-hardening region.

    DOI: 10.1021/acs.macromol.3c00197

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    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85152144512&origin=inward

  • Anomalous Strain Recovery after Stress Removal of Graded Rubber 査読

    Do Q.V., Kida T., Yamaguchi M., Washizu K., Nagase T., Tada T.

    Polymers   14 ( 24 )   2022年12月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Polymers  

    Mechanical responses after the uniaxial deformation of graded styrene–butadiene rubber (SBR) with a gradient in the crosslink points in the thickness direction were investigated as compared with those of homogenously vulcanized SBR samples. The elongational residual strain of a graded sample was found to depend on the part with a high crosslink density. Therefore, it showed good rubber elasticity. After stress removal, moreover, the graded sample showed a marked warpage. This suggested that shrinking stress acted on the surface with a high crosslink density, which would avoid a crack growth on the surface. The sample shape was then recovered to be flat very slowly, indicating that the shrinking stress worked for a long time. This unique rubber elasticity, i.e., slow strain recovery with an excellent strain recovery, makes graded rubber highly significant.

    DOI: 10.3390/polym14245477

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85144618341&origin=inward

  • Novel Transparent Films Composed of Bisphenol-A Polycarbonate and Copolyester 査読

    Hasegawa H., Kida T., Yamaguchi M.

    Polymers   14 ( 19 )   2022年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Polymers  

    In this paper, the structure and properties of transparent films composed of bisphenol-A polycarbonate (PC) and a commercially available copolyester, poly(1,4-cyclohexanedimethanol-co-2,2,4,4-tetramethyl-1,3-cyclobutanediol-co-terephthalate) (CPE), were studied. Both PC and CPE films are known to be transparent with good mechanical toughness. It was found that PC/CPE (50/50) showed miscibility in both the molten and solid states, indicating that there is a high possibility for the blend system to be miscible in the whole blend ratios. Because of the miscibility, the blend films showed no light scattering originating from phase separation. The mechanical properties of the films, such as Young’s modulus, yield stress, and strain at break, were determined by the blend ratio, and the glass transition temperature increased with the PC content, which corresponded well with the values predicted by the Fox equation. These results demonstrate that the thermal and mechanical properties of the films can only be controlled by the blend ratio. Since these transparent films showed excellent mechanical toughness irrespective of the blend ratios, they can be employed in various applications.

    DOI: 10.3390/polym14194146

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85139836016&origin=inward

  • Evaluation of Rheological Properties and Generation of Cross Orientation of Lamellae and Amorphous Chains in a Thermoplastic Polyester Elastomer 査読

    Yamada T., Yamaguchi M., Kida T.

    ACS Applied Polymer Materials   4 ( 9 )   6322 - 6331   2022年9月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ACS Applied Polymer Materials  

    Cross orientation between lamellae and amorphous chains was generated by forming residual crystals during extrusion and melt stretching under temperature-controlled processing conditions in a thermoplastic polyester elastomer (TPEE). Some crystals were not completely melted at a certain temperature slightly higher than the melting temperature of the sample during a heating process, and the survived crystals are called residual crystals. The TPEE exhibited prolonged relaxation at the temperature slightly higher than the melting temperature owing to the formation of the network structure composed of the residual crystals. The formation of the weak network affected the processability during extrusion, such as the swell ratio and the drawdown force. Although polarized microscopy images apparently showed that the average molecular orientation was along the drawing direction, it was found that the lamellar crystals oriented orthogonal to the fiber axis to reduce the hydrodynamic force during extrusion according to the results of multiple structural analyses. The orthogonal orientation of the lamellar crystals should be caused by the high aspect ratio of the lamellar crystals grown from the residual crystals. The orthogonal orientation resulted in a high Young's modulus and yield stress. The method for generating cross orientation of crystalline and amorphous chains will be applied to the preparation of high-performance fibers with high strength and modulus.

    DOI: 10.1021/acsapm.2c00508

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85137278482&origin=inward

  • Crystallinity enhancement of extruded polypropylene containing poly(vinyl alcohol) fibers prepared in situ 査読

    Nishikawa R., Eno A., Janchai K., Han R., Kida T., Mori T., Aridome N., Miyamoto A., Yamaguchi M.

    Polymer   254   2022年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Polymer  

    The present paper describes a novel method for reinforcing isotactic polypropylene (PP) by adding poly(vinyl alcohol) (PVA) fibers prepared by melt-stretching. Low-viscosity PVA droplets were deformed into fibers in the molten PP by melt-stretching them beyond the melting point of PVA. When the obtained composite was extruded below the melting point of PVA, the fibers became oriented toward the flow direction. The PVA demonstrated marked nucleating activity with regard to PP crystallization, which was further promoted by enlargement of the surface area by fibrillization. As a result, there was virtually no orientation relaxation of the PP chains with an increase in crystallinity, which explains the improvement in rigidity of the reinforced composite.

    DOI: 10.1016/j.polymer.2022.125043

    Scopus

    その他リンク: https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85132348667&origin=inward

  • Rheo-Raman Spectroscopic Study of Microscopic Deformation Behavior of Low- and High-Density Polyethylene Solids under Uniaxial Deformation 査読

    Takumitsu Kida, Yusuke Hiejima, Koh-hei Nitta, Masayuki Yamaguchi

    Nihon Reoroji Gakkaishi (J Soc Rheol Jpn)   60 ( 3 )   287 - 294   2022年6月

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    担当区分:筆頭著者, 責任著者   記述言語:英語   掲載種別:研究論文(学術雑誌)  

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  • Evaluation of microscopic structural changes during strain hardening of polyethylene solids using In situ Raman, SAXS, and WAXD measurements under step-cycle test 査読

    Kida T., Hiejima Y., Nitta K.h., Yamaguchi M.

    Polymer   250   2022年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Polymer  

    We have examined the mechanism of strain hardening of polyethylene (PE) using a step-cycle test with in situ Raman spectroscopy, small-angle X-ray scattering, and wide-angle X-ray diffraction measurements. A stable fibrillar structure was formed at the onset of strain hardening. The fraction of the long-consecutive trans chains increased and decreased with increasing and decreasing strain during the stretching and unloading steps, respectively. The peak shift of the C–C stretching mode showed a red shift by applying the stretching stress to the specimen, accompanied by the broadening of the peak width. The broadening of the Raman band is interpreted as the strong stretching load becoming concentrated on the taut-tie chains. According to these results, we concluded that the strain hardening was caused by the increment of the modulus resulting from the increase in the number of taut-tie chains caused by chain pull-out from the crystalline structure.

    DOI: 10.1016/j.polymer.2022.124869

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  • Role of Rigid–Amorphous chains on mechanical properties of polypropylene solid using DSC, WAXD, SAXS, and Raman spectroscopy 査読

    Kida T., Yamaguchi M.

    Polymer   249   2022年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Polymer  

    We evaluated the rigid–amorphous (RA) fraction of isotactic polypropylene (iPP) samples by various measurement techniques and investigated the role of the RA chains on the mechanical properties of iPP. The RA fraction was increased by annealing above the α-relaxation temperature, although the RA fraction was almost independent of the molecular weight. The RA fraction obtained by differential scanning calorimetry increased linearly with the number of consecutive helical chains with 12–14 monomer units, suggesting that the RA chains are attributable to crystalline defects. Moreover, the α-relaxation temperature varied linearly with the RA fraction; the RA chains present as crystalline defects were removed from the crystalline structure by α relaxation. The yielding region of the stress–strain curve became broad by increasing the RA fraction; the fragmentation strength of the lamellar crystals was widely distributed owing to the large number of crystalline defects.

    DOI: 10.1016/j.polymer.2022.124834

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  • Star polymers with norbornene/1-octene gradient copolymer arms synthesized by an ansa-fluorenylamidodimethyltitanium-[Ph<inf>3</inf>C][B(C<inf>6</inf>F<inf>5</inf>)<inf>4</inf>] catalyst system 査読

    Yuan H., Kida T., Tanaka R., Cai Z., Nakayama Y., Kihara S.i., Shiono T.

    Polymer   249   2022年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Polymer  

    Cyclic olefin copolymers (COCs), among which ethylene (E)/norbornene (NB) copolymer have been commercialized, are novel optical plastics but their brittleness narrows their application fields. In this research, star polymers with NB/1-octene (O) gradient copolymer arms and cross-linked cores were synthesized by adding norbornadiene (NBD)/E or 1,11-dodecadiene (DOD) after NB/O copolymerization using a (tBuNSiMe2Flu)TiMe2 (I)-[Ph3C][B(C6F5)4] catalyst system with 2,6-di-tert-butyl-4-methylphenol-treated tri-n-octylaluminum (Oct3Al/BHT) as a scavenger. The obtained star polymers possessed the O-rich soft segments close to the core and the NB-rich hard segments in the outer layer. The DOD-cored star polymers had a larger number of arms (15) and a higher star polymer content (68 wt%) than the NBD/E-cored ones (6 and 58 wt%, respectively). The films of the mixtures of the star and the corresponding arm polymers were molded by a melt-pressing procedure. The tensile properties of the films of the DOD-cored star polymer mixtures were significantly improved compared to those of the arm polymers. The Young's modulus, yield stress, strength, and strain at break were controlled by the NB content, the arm length, and the gradient structure of the arms. These results clarified the novelty of the star-shaped NB/α-olefin copolymers and would expand the application fields of COCs.

    DOI: 10.1016/j.polymer.2022.124844

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  • Segregation Behavior of Miscible PC/PMMA Blends during Injection Molding 査読

    Moonprasith N., Date J., Sako T., Kida T., Hiraoka T., Yamaguchi M.

    Materials   15 ( 9 )   2022年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Materials  

    Miscible blends composed of bisphenol-A polycarbonate (PC) and poly(methyl methacrylate) (PMMA), in which one of them has low molecular weight, were employed to study the surface segregation behavior during flow. The blend samples showed typical rheological behaviors, such as simple polymer melts without a long-time relaxation mechanism ascribed to phase separation, demonstrating that they were miscible. After injection molding, the amounts of a low molecular weight component on the blend surface were found to be larger than the actual blend ratio. Because the injection-molded products were transparent despite a huge difference in refractive indices between PC and PMMA, they showed no phase separation. This result demonstrated that surface segregation of a low molecular weight component occurred under flow field, which expands the material design such as tough plastics with good scratch resistance and optical fibers with tapered refractive index.

    DOI: 10.3390/ma15092994

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  • Viscoelastic Properties of Fully Biomass-Based Transparent Plastic Comprising Cellulose Acetate and Citrate Ester 査読

    Kimura T., Kida T., Yamaguchi M.

    Materials   15 ( 9 )   2022年5月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Materials  

    Viscoelastic properties including melt processability were evaluated for a fully biomass-based glassy plastic comprising cellulose acetate (CA) and triethyl citrate (TEC). The TEC exerted an excellent plasticizing effect without dissolving the CA crystals. Pure CA has poor melt processability. In contrast, the TEC-plasticized CA had good melt-processability at 205◦C, which is lower than the degradation temperature of CA. Extrusion was possible even at 1000 s−1 without any flow instabilities, similar to conventional plastics showing good processability at extrusion. Furthermore, there was marked strain-hardening behavior in the transient elongational viscosity, suggesting that various processing operations are possible, such as a long-chain branched polymer. This biomass-based plastic can be used as a substitute for conventional glassy plastics because it is highly transparent and its softening temperature is above 100◦C.

    DOI: 10.3390/ma15093038

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  • Complicated Structure Change during Capillary Extrusion of Binary Blends of Polycarbonate and Poly(methyl methacrylate) 査読

    Yamaguchi M., Nakamura K., Kimura T., Moonprasith N., Kida T., Tsubouchi K., Narita T., Hiraoka T.

    Materials   15 ( 8 )   2022年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Materials  

    The effects of pressure and shear rate on the miscibility of binary blends comprising bisphenol-A polycarbonate (PC) and low molecular weight poly(methyl methacrylate) (PMMA) were investigated using a capillary rheometer. Both pressure and shear rate affected the miscibility. The examination of an extruded strand of the blend provided information about the cause of the phase change. Under high pressure, pressure-induced demixing occurred at temperatures below the lower critical solution temperature (LCST) of the blend. Consequently, the extruded strand became opaque throughout. During shear-induced mixing/demixing, a part of the strand became opaque because of the distribution of the shear rate in the strand. For example, during shear-induced demixing, only the exterior of the strand, i.e., the high shear rate region, became opaque. Above the LCST, shear-induced mixing occurred, and only the center region of the strand became opaque.

    DOI: 10.3390/ma15082783

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  • Crystallization behavior of isotactic polypropylene containing a fibrous nucleating agent in a flow field 査読

    Janchai K., Kida T., Inoue T., Iwasaki S., Yamaguchi M.

    Polymer Journal   54 ( 3 )   367 - 375   2022年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Polymer Journal  

    The crystallization behavior of isotactic polypropylene containing a fibrous nucleating agent in a flow field was investigated using a polarized optical microscope equipped with a parallel-plate shear device. The addition of the fibrous nucleating agent greatly enhanced the crystallization rate, although isotactic polypropylene crystallization without the nucleating agent was enhanced after exposure to shear flow at a high shear rate. The sample with the nucleating agent demonstrated high molecular orientation to the flow direction after shear flow, even at a low shear rate. This was attributed to the formation of a pseudo shish-kebab structure, in which the fibrous nucleating agent acts as the shish. Moreover, the high level of molecular orientation without spherulitic morphology was responsible for the reduced light scattering, which resulted in good transparency.

    DOI: 10.1038/s41428-021-00596-7

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  • Raman Spectroscopic Analyses of Structure-Mechanical Properties Relationship of Crystalline Polyolefin Materials 招待 査読

    Takumitsu Kida

    Nihon Reoroji Gakkaishi (J Soc Rheol Jpn)   50 ( 1 )   21 - 29   2022年2月

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    担当区分:筆頭著者, 責任著者   記述言語:英語   掲載種別:研究論文(学術雑誌)  

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  • Cyclic Olefin Copolymer Bearing Pendant Fluorenyl Groups with High Refractive Index and Low Chromatic Dispersion 査読

    Yuan H., Kida T., Ishitobi Y., Tanaka R., Yamaguchi M., Nakayama Y., Shiono T.

    Macromolecules   55 ( 1 )   125 - 132   2022年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Macromolecules  

    Copolymerization of norbornene (NB) and fluorene-containing alkene comonomers using the Me2Si(Flu)(NtBu)TiMe2 complex as a catalyst was investigated. The copolymerization successfully proceeded at any monomer feed ratio in high activity and gave copolymers with various comonomer contents. The structure of these copolymers would be gradient because NB was preferentially consumed in a quasi-living polymerization system. Two relaxation processes at 100-150 and 270-300 °C in dynamic mechanical analysis, which show phase-separation of the copolymer, supported the formation of the gradient structure. The obtained copolymers showed a high refractive index as hydrocarbons and extremely low photoelasticity (<10-11 Pa-1). For reducing the photoelasticity, a monomer design free from reactive tertiary carbons would be important.

    DOI: 10.1021/acs.macromol.1c02101

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  • Effect of thermal history on the structure and mechanical properties of a thermoplastic polyester elastomer 査読

    Yamada T., Kida T., Yamaguchi M.

    Polymer   238   2022年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Polymer  

    An appropriate processing protocol was proposed to improve the rubber elasticity of a thermoplastic polyester elastomer (TPEE). Rheology measurements at the processing temperature and thermal measurements determined the critical temperature at which small numbers of crystals exist. It was found from dynamic mechanical analyses, wide- and small-angle X-ray measurements, and electron microscope observations that cooling from the critical temperature markedly promoted the crystallization of hard segments. Moreover, tensile tests revealed that the modulus and yield stress increased. Most importantly, compared with films obtained by cooling from high temperatures, the residual strain at a fixed stress was low—i.e., the rubber elasticity was improved owing to its well-developed crystalline structure. These effects were accelerated by a more optimized process—i.e., subsequent heating at slightly below the critical temperature. The technique is noteworthy because a TPEE with high modulus generally shows poor elasticity.

    DOI: 10.1016/j.polymer.2021.124376

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  • Effect of Swelling and Deswelling on the Elasticity of Polyacrylonitrile Gels Prepared by Freezing and Thawing Techniques 査読

    Tanaka Y., Furui S., Nakashima N., Nakajima S., Kida T.

    Journal of Macromolecular Science, Part B: Physics   61 ( 9 )   1046 - 1061   2022年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Journal of Macromolecular Science, Part B: Physics  

    The repeating cycle of freezing and thawing brings about a physical gelation for the solutions of polyacrylonitrile (PAN) in N, N-dimethylacetamide (DMA) for appropriate concentrations. It was revealed from wide-angle-X-ray diffraction that the PAN molecules were cross-linked by the crystallization to form a network through the freezing and thawing steps. The profiles of small-angle-X-ray scattering for the gels showed the excess scattering from the network structure formed through gelation, which could not be observed for the pure PAN solution. A reversible swelling and shrinking were observable for the PAN gel as a function of the relative content of DMA and benzene by varying the mixing ratio. The degree of swelling measured by weight, for the swollen and shrunk gels, was in a range from 0.7 to 8. A scaling relation appeared for the gel swelling between the PAN volume fraction (ϕ) and the shear moduli (G) which was measured by tensile and indentation tests, as G = G s ×(ϕ)s; G s= 1200 kPa and s = 2.26 ± 0.23. A discussion is given on the value of the scaling exponent, s, on the basis of the conformation of flexible chain molecules in solution and the analogy in the microscopic and macroscopic properties between semidilute polymer solutions and gels.

    DOI: 10.1080/00222348.2022.2127264

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  • Rheo-Raman Spectroscopic Study of Microscopic Deformation Behavior of Lowand High-Density Polyethylene Solids under Uniaxial Deformation 査読

    Kida T., Hiejima Y., Nitta K.H., Yamaguchi M.

    Nihon Reoroji Gakkaishi   50 ( 3 )   287 - 294   2022年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Nihon Reoroji Gakkaishi  

    The microscopic deformation behaviors of high-density polyethylene (HDPE) and low-density polyethylene (LDPE) under uniaxial stretching were investigated using rheo-Raman spectroscopy. The crystalline chains of LDPE were oriented uniaxially into the stretching direction beyond the first yielding point, which was accompanied by applying stretching load to the crystalline chains. In contrast, at the first yielding point of HDPE, the orientation of crystalline chains was suppressed and compression load was applied to the amorphous and crystalline chains owing to lateral shrinkage of the specimen. Additionally, the orthorhombic crystalline regularity was significantly disordered at the first yielding point for HDPE, concomitant with the fragmentation of the rigid lamellar crystals. In comparison, the disordering of the crystalline regularity of LDPE was induced at the second yielding point, when the orientation of the crystalline chains was nearly complete, owing to the application of a strong stretching load to the highly oriented crystalline chains.

    DOI: 10.1678/rheology.50.287

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  • Raman Spectroscopic Analyses of Structure–Mechanical Properties Relationship of Crystalline Polyolefin Materials 査読

    Kida T.

    Nihon Reoroji Gakkaishi   50 ( 1 )   21 - 29   2022年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Nihon Reoroji Gakkaishi  

    Raman spectroscopy is a vibrational spectroscopic technique that is widely used for analyses of the chemical structures and morphologies of polymeric materials. The peak position and peak area of each Raman band are influenced by microscopic deformations of molecular chain e.g. load-sharing, orientation, and conformational state. In particular, Raman spectroscopic analysis has been used to investigate the structure–mechanical properties relationship of semi-crystalline polyolefins (POs) because the C–C stretching mode, which is the main chain vibration of POs, is strongly Raman-active. The present review summarizes recent Raman spectroscopic analyses of the structure–mechanical properties relationship of POs.

    DOI: 10.1678/rheology.50.21

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  • Polymerization of Styrene Derivatives Using Anilinonaphthoquinone-Ligated Nickel Complexes and Thermal/Rheological Properties of the Produced Polymers 査読

    Chowdhury S.I., Kida T., Tanaka R., Nakayama Y., Shiono T.

    Macromolecular Chemistry and Physics   223 ( 1 )   2022年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Macromolecular Chemistry and Physics  

    Polystyrenes (PStX, X = -H, -OMe, -Me, or -Cl at 4-position) are synthesized by the use of anilinonaphthoquinone-ligated nickel complexes [Ni(C10H5O2NAr)(Ph)(PPh3): 1a, Ar = C6H3-2,6-iPr; 1b, Ar = C6H2-2,4,6-Me; 1c, Ar = C6H5] activated with modified methylaluminoxane (MMAO) in toluene. The polymer yield is dependent on the substituent X and decreases in the following order: -OMe > -Me > -H >> -Cl. The highest weight-average molecular weight (Mw) of 107 000 with polydispersity (Ð) of 1.4 is achieved for PStOMe by the 1a-MMAO catalytic system. 13C NMR analysis indicated that the polymers obtained at 70 °C are atactic but those obtained at 0 °C are isotactoid (isotactic triad ≈ 74 ̶ 82 %), which depended on X. The linear viscoelasticity measurement is also performed to investigate the influences of the substituent on the rheological properties. The critical molecular weight of the chain entanglement of PStOMe is higher than that of PStMe, which should be due to the suppression of the chain entanglement by the methoxy group.

    DOI: 10.1002/macp.202100402

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  • Effect of Ultra-High-Molecular-Weight Molecular Chains on the Morphology, Crystallization, and Mechanical Properties of Polypropylene 査読 国際誌

    Takumitsu Kida, Takeyoshi Kimura, Ayaka Eno, Khunanya Janchai, Masayuki Yamaguchi, Yasuhiko Otsuki, Tokutaro Kimura, Tomoaki Mizukawa, Tomoya Murakami, Kazuki Hato, Tomoya Okawa

    Polymers   13 ( 23 )   4222 - 4222   2021年12月

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    担当区分:筆頭著者, 責任著者   記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:MDPI AG  

    The effects of the ultra-high-molecular-weight (UHMW) component of polypropylene (PP) on its rheological properties, crystallization behavior, and solid-state mechanical properties were investigated using various measurement techniques. The terminal relaxation time—determined by measuring the linear viscoelasticity—was increased by adding the UHMW component. The increase in the melt elasticity produced by adding the UHMW component was observed by measuring the steady-state shear flow, although the shear viscosity was not greatly affected. Owing to the long characteristic time of the Rouse relaxation of the UHMW component, PP with the UHMW component formed highly oriented structures through a shear-induced crystallization process. The addition of the UHMW component enhanced the orientation and regularity of crystalline structure for extruded films. Therefore, the Young′s modulus, yield stress, and strength were higher in the PP film containing the UHMW component than in one without the UHMW component, irrespective of the direction of tensile deformation.

    DOI: 10.3390/polym13234222

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  • 分子量分布および短鎖分岐構造がポリエチレンの一軸引張り挙動に与える影響 査読

    木田拓充

    次世代ポリオレフィン総合研究   14   45 - 49   2021年12月

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    担当区分:筆頭著者, 責任著者   記述言語:日本語   掲載種別:研究論文(学術雑誌)  

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  • Impact of Magnesium Salt on the Mechanical and Thermal Properties of Poly(vinyl alcohol) 査読

    Riza Asmaa Saari, Muhammad Shahrulnizam Nasri, Takumitsu Kida, Masayuki Yamaguchi

    Polymers   13 ( 21 )   3760 - 3760   2021年10月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:MDPI AG  

    The effects of magnesium salts with various anion species on the structure and properties of a poly(vinyl alcohol) (PVA) film were studied. The glass transition temperature of the PVA film increased following the addition of a magnesium salt. Furthermore, the salt greatly enhanced the modulus and yield stress and reduced the crystallinity of the film. These effects were attributed to the strong ion–dipole interactions between the magnesium salts and the PVA chains. The strength of interaction, i.e., the reduction of segmental motions, depended on the anion species in the following order: Mg(ClO4)2, MgBr2, MgCl2, Mg(CH3COO)2, and MgSO4. The order corresponded to the Hofmeister series, which predicts the ability to break the structure of water.

    DOI: 10.3390/polym13213760

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  • Rheological properties of linear and short-chain branched polyethylene with nearly monodispersed molecular weight distribution 査読

    Takumitsu Kida, Yuya Doi, Ryo Tanaka, Takashi Uneyama, Takeshi Shiono, Yuichi Masubuchi

    Rheologica Acta   60   511 - 519   2021年7月

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    担当区分:筆頭著者, 責任著者   記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Springer Science and Business Media LLC  

    DOI: 10.1007/s00397-021-01286-0

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  • Improving the strength of polyethylene solids by simple controlling of the molecular weight distribution 査読

    Takumitsu Kida, Ryo Tanaka, Yusuke Hiejima, Koh-hei Nitta, Takeshi Shiono

    Polymer   218   123526 - 123526   2021年3月

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    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier BV  

    We prepared model polyethylene (PE) samples that contain the controlled-amounts of the high-molecular-weight component by blending a monodispersed PE into a polydispersed PE, to elucidate the influence of the high-molecular-weight component of a polymer on its mechanical properties. The strength and strain-hardening modulus were significantly enhanced by the addition of a monodispersed PE of sufficiently high molecular weight, and the critical value of M was determined to be ~3.0 × 10 . The improved strength and strain-hardening modulus are attributed to higher amounts of inter-cluster links that bridge adjacent lamellar cluster units because these links act as stress transmitters between these units. w 5

    DOI: 10.1016/j.polymer.2021.123526

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  • Incorporation of Boronic Acid Functionality into Isotactic Polypropylene and Its Application as a Cross-Linking Point 査読

    Ryo Tanaka, Hiroya Fujii, Takumitsu Kida, Yuushou Nakayama, Takeshi Shiono

    Macromolecules   54 ( 3 )   1267 - 1272   2021年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:American Chemical Society (ACS)  

    DOI: 10.1021/acs.macromol.0c02686

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  • Synthesis of thermoplastic elastomers with high biodegradability in seawater 査読

    Lamya Zahir, Takumitsu Kida, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama

    Polymer Degradation and Stability   184   109467 - 109467   2021年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier BV  

    As a promising biodegradable and biorenewable alternative to ubiquitous petrochemical plastics, poly(L-lactide) (PLLA) can be widely employed in biomedical and pharmaceutical fields. In this work, triblock copolymers, poly(L-lactide)-b-poly(2-methyl-1,3-propanediyl adipate)-b-poly(L-lactide) (PLLA-b-PMPA-b-PLLA)s, were synthesized by two-step polymerization from 2-methyl-1,3-propanediol (MP), adipic acid (AA) and L-lactide (LLA) as new biodegradable thermoplastic elastomers. The copolymers exhibited glass-transition temperature at below -40 degrees C and melting temperature at 140-160 degrees C. These copolymers showed much higher elongation at break and lower tensile modulus than those of PLLA. Enzymatic degradation tests of the obtained copolymers were performed using proteinase K and lipase PS as catalysts in hydrolysis reaction to demonstrate rapid degradation for these copolymers. Seawater biodegradability test was conducted for 28 days for each sample. The triblock copolymer and PMPA homopolymer were found to show about 50% biodegradation within 28 days representing very high biodegradable property in sea-water. (C) 2020 The Authors. Published by Elsevier Ltd.

    DOI: 10.1016/j.polymdegradstab.2020.109467

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  • Synthesis, Properties, and Biodegradability of Thermoplastic Elastomers Made from 2-Methyl-1,3-propanediol, Glutaric Acid and Lactide 査読

    Lamya Zahir, Takumitsu Kida, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama

    Life   11 ( 1 )   43 - 43   2021年1月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:MDPI AG  

    An innovative type of biodegradable thermoplastic elastomers with improved mechanical properties from very common and potentially renewable sources, poly(L-lactide)-b-poly(2-methyl-1,3-propylene glutarate)-b-poly(L-lactide) (PLA-b-PMPG-b-PLA)s, has been developed for the first time. PLA-b-PMPG-b-PLAs were synthesized by polycondensation of 2-methyl-1,3-propanediol and glutaric acid and successive ring-opening polymerization of L-lactide, where PMPG is an amorphous central block with low glass transition temperature and PLA is hard semicrystalline terminal blocks. The copolymers showed glass transition temperature at lower than −40 °C and melting temperature at 130–152 °C. The tensile tests of these copolymers were also performed to evaluate their mechanical properties. The degradation of the copolymers and PMPG by enzymes proteinase K and lipase PS were investigated. Microbial biodegradation in seawater was also performed at 27 °C. The triblock copolymers and PMPG homopolymer were found to show 9–15% biodegradation within 28 days, representing their relatively high biodegradability in seawater. The macromolecular structure of the triblock copolymers of PLA and PMPG can be controlled to tune their mechanical and biodegradation properties, demonstrating their potential use in various applications.

    DOI: 10.3390/life11010043

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  • Microstructural Interpretation of Influences of Molecular Weight on the Tensile Properties of High-Density Polyethylene Solids Using Rheo-Raman Spectroscopy 査読

    Takumitsu Kida, Yusuke Hiejima, Koh-hei Nitta

    Macromolecules   54 ( 1 )   225 - 234   2021年

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    担当区分:筆頭著者, 責任著者   記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:American Chemical Society (ACS)  

    DOI: 10.1021/acs.macromol.0c02124

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  • Synthesis and properties of block copolymers composed of norbornene/higher α-olefin gradient segments using ansa-fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4] catalyst system 査読

    Haobo Yuan, Takumitsu Kida, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono

    Polymer Chemistry   12 ( 2 )   189 - 195   2021年

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    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Royal Society of Chemistry (RSC)  

    <p>A series of di- and triblock copolymers composed of gradient norbornene (NB)/α-olefin segments were synthesized by a (<italic>t</italic>-BuNSiMe<sub>2</sub>Flu)TiMe<sub>2</sub>-based catalyst and their physical and mechanical properties were investigated.</p>

    DOI: 10.1039/d0py01370f

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  • Radial distribution functions of entanglements in primitive chain network simulations 査読

    Yuichi Masubuchi, Takumitsu Kida, Yuya Doi, Takashi Uneyama

    Nihon Reoroji Gakkaishi (J Soc Rheol Jpn)   49 ( 5 )   337 - 345   2021年

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:SOC RHEOLOGY, JAPAN  

    Although the entanglement network among polymers has been widely investigated, the spatial distribution of entanglement nodes has been rarely discussed. In this study, we obtained the radial distribution functions (RDFs) for the entanglement nodes from the snapshots of multi-chain slip-link simulations. The model employed in this study is the primitive chain network (PCN) model, which has been validated to reproduce the entangled polymer dynamics semi-quantitatively. The statistics of captured entanglement networks were compared to those reported for the primitive path network extracted by the CReTA procedure from the full-atomistic molecular model of a polyethylene melt. In the range of distance longer than the average strand length, the network structure from PCN does not show any structural correlation, and the intra-chain correlation is close to that for Gaussian chains with non-interacting slip-links. These features are consistent with the CReTA network and the conventional assumptions made for single-chain models. Meanwhile, in the short-range, the structural correlation in PCN is much weaker than that in CReTA. This discrepancy is because the short-range structure in PCN is realized as a result of imposed fluctuations, whereas it is determined by the minimization of the primitive path in CReTA.

    DOI: 10.1678/rheology.49.337

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  • Synthesis and properties of biodegradable thermoplastic elastomers using 2-Methyl-1,3-propanediol, succinic acid and lactide 査読

    Lamya Zahir, Takumitsu Kida, Ryo Tanaka, Yuushou Nakayama, Takeshi Shiono, Norioki Kawasaki, Naoko Yamano, Atsuyoshi Nakayama

    Polymer Degradation and Stability   181   109353 - 109353   2020年11月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier BV  

    Triblock copolymers, poly(L-lactide)-b-poly(2-methyl-1,3-propanediyl succinate)-b-poly(L-lactide) (PLLA-b-PMPS-b-PLLA), were synthesized as new biodegradable thermoplastic elastomers by two-step polymerization. In the first step, hydroxy-telechelic poly(2-methyl-1,3-propanediyl succinate) (PMPS) was synthesized from 2-methyl-1,3-propanediol (MP, small excess) and succinic acid (SA) using two-stage reaction of esterification and simple polycondensation processes. In the second step, plant derived L-lactide (LLA) was polymerized using the bifunctional PMPS as a macroinitiator to synthesize PLLA-b-PMPS-b-PLLA triblock copolymers. The structures of the triblock copolymers as well as the PMPS macroinitiator were characterized by NMR and GPC analysis. PMPS is an amorphous polymer with T-g at lower than -24 degrees C. The triblock copolymers also exhibited low T-g for the PMPS segment at lower than -20 degrees C as well as T-m, at around 150 degrees C for the PLLA segment. The tensile tests of the triblock copolymers demonstrated their low modulus and high elongation. The biodegradation tests of these polymers were also performed using enzymes and seawater to reveal their biodegradability. (C) 2020 The Authors. Published by Elsevier Ltd.

    DOI: 10.1016/j.polymdegradstab.2020.109353

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  • Microscopic Origin of Elastic and Plastic Deformation in Poly(Ether-Block-Amide) Elastomers under Various Conditions 査読

    Takumitsu Kida, Keisuke Hamasaki, Yusuke Hiejima, Shuichi Maeda, Koh-hei Nitta

    Nihon Reoroji Gakkaishi   48 ( 3 )   153 - 160   2020年6月

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    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Society of Rheology Japan  

    DOI: 10.1678/rheology.48.153

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  • Synthesis and Properties of Gradient Copolymers Composed of Norbornene and Higher α-Olefins Using an ansa-Fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)4] Catalyst System 査読

    Haobo Yuan, Takumitsu Kida, Hyunchul Kim, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono

    Macromolecules   53 ( 11 )   4323 - 4329   2020年6月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:American Chemical Society (ACS)  

    The copolymerization of norbornene (NB) and various alpha-olefins [1-octene (O), 1-decene (De), and 1-dodecene (Do)] was achieved with high activity using ((t)BuNSiMe(2)Flu)TiMe2 (1)-[Ph3C][B(C6F5)(4)] and 2,6-bis(1,1-dimethylethyl)-4-methylphenol (BHT)-treated tri-i-butylaluminum ((Bu3Al)-Bu-i) or tri-n-octylaluminum (Oct(3)Al) as a scavenger. The catalytic systems gave NB/alpha-olefin copolymers with number-average molecular weights over 100,000 and polydispersity indices below 1.3. The copolymers possessed the gradient structure starting from the NB-rich segment to the alpha-olefin-rich terminal because of the difference of the monomer reactivity ratios between NB and alpha-olefins. Films of the copolymers were successfully molded using a melt-pressing procedure. The strain at the break of the copolymer films increased with the length of the alkyl group of the alpha-olefin accompanied by a decrease in strength. The tensile properties of the copolymers are controlled by the NB content and the M-n value. The copolymer films showed transmittance of up to 80% in the visible-light range.

    DOI: 10.1021/acs.macromol.0c00431

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  • In situ Raman Spectroscopic Observation of Polymer Chains in Semi-Crystalline Polyethylene Solids 査読

    Zeitschrift für Physikalische Chemie   In Press   2020年3月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)  

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  • Rheo-Raman spectroscopic study of plasticity and elasticity transformation in poly(ether-block-amide) thermoplastic elastomers 査読

    Takumitsu Kida, Taisei Sasaki, Yusuke Hiejima, Shuichi Maeda, Koh-hei Nitta

    Polymer   189   122128   2020年1月

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    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)  

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  • Effect of the number of arms on the mechanical properties of a star-shaped cyclic olefin copolymer 査読

    Takumitsu Kida, Ryo Tanaka, Koh-hei Nitta, Takeshi Shiono

    Polymer Chemistry   2019年8月

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    出版者・発行元:Royal Society of Chemistry ({RSC})  

    DOI: 10.1039/C9PY01186B

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  • Rheo-Raman Spectroscopic Study on Uniaxial Deformation Behavior of High-Density Polyethylene Solids with Various Molecular Weight Distributions 査読

    Takumitsu Kida, Yusuke Hiejima, Koh-hei Nitta

    Macromolecules   2019年6月

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    出版者・発行元:American Chemical Society ({ACS})  

    DOI: 10.1021/acs.macromol.8b02740

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  • ラマン分光法を用いた結晶性ポリオレフィン材料の微視的変形挙動の解析 査読

    木田拓充

    高分子論文集   75 ( 6 )   497 - 506   2018年11月

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    記述言語:日本語   掲載種別:研究論文(学術雑誌)  

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  • Microscopic structural changes during photodegradation of low-density polyethylene detected by Raman spectroscopy 査読

    Yusuke Hiejima, Takumitsu Kida, Kento Takeda, Toshio Igarashi, Koh-hei Nitta

    Polymer Degradation and Stability   150   67 - 72   2018年4月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Elsevier Ltd  

    Raman spectroscopy has been used to reveal the microscopic structural changes of low-density polyethylene under ultraviolet irradiation. The fraction of non-crystalline consecutive trans chains (the molecular chains in the trans conformation separate from the orthorhombic crystalline phase) drastically decreases at ∼600 h, together with a decrement in the molecular weight and an increment in the crystallinity owing to chemicrystallization. This suggests that short trans chains are prolonged to form consecutive trans chains before chemicrystallization. Moreover, gradual increases of the stretching and compression stresses are observed on the trans and amorphous chains, respectively. These conformational changes are detected by Raman spectroscopy even in the early stage of photodegradation. Chemicrystallization at ∼600 h is accompanied by structural changes, such as shortening of the interchain distance of the lamellar crystals and thinning of the amorphous layer, which induce formation of surface cracks on the macroscopic specimen.

    DOI: 10.1016/j.polymdegradstab.2018.02.010

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    その他リンク: http://orcid.org/0000-0002-9494-3004

  • In Situ Monitoring of Orientation Parameters and Orientation Distribution Functions of Polyethylenes during Tensile Tests 査読

    Yusuke Hiejima, Takumitsu Kida, Koh-Hei Nitta

    Macromolecular Symposia   377 ( 1 )   2018年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Wiley-VCH Verlag  

    In situ polarized Raman spectroscopy is applied for the tensile deformation of high- and low-density polyethylenes (HDPE and LDPE), and the orientation parameters as well as the orientation distribution function (ODF) are determined. While random orientation is maintained in the elastic region, the orientation of the polymer chains begins after the first yield point. The ODF for LDPE shows a peak at the stretching direction throughout the elongation process, and the maximum value of the ODF monotonously increases with the strain. For HDPE, the ODF in the yielding region has a broad peak at an intermediate angle of 30–70° from the stretching direction, while the orientation at the stretching direction is restored in the strain-hardening region. The tilted orientation is explained with the concept of the lamellar cluster units formed in the yielding region after the collapse of the spherulites. The HDPE with lower molecular weight and that with wider molecular weight distribution show high orientation, which is explained with the smaller size of the lamellar cluster units and the higher network density in the amorphous phase, respectively.

    DOI: 10.1002/masy.201700020

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    その他リンク: http://orcid.org/0000-0002-9494-3004

  • Rheo-Raman Study of Isotactic Polypropylene Under Tensile Deformation 査読

    Takumitsu Kida, Yusuke Hiejima, Koh-Hei Nitta

    Macromolecular Symposia   377 ( 1 )   2018年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:Wiley-VCH Verlag  

    The microscopic deformation behaviors such as the load sharing and the molecular orientation of the crystalline chains of isotactic polypropylene under tensile stretching are examined by using rheo-Raman spectroscopy. The Raman bands assigned to the skeletal CC stretching modes show blue shifts after the yielding, indicating that the stretching stress is applied to the main chain. The CH3 rocking band shows red shift in the yielding region, suggesting that the compression stress is applied in the interchain direction of the crystalline chains. While the molecular orientation of the crystalline chains begins after the first yield point, the crystalline orientation is hindered due to the existence of the rigid and bulky lamellar cluster units. Beyond the yielding region, the orientation toward the stretching direction proceeds rapidly, and the crystalline chains simply orient in the stretching direction in the highly strained region.

    DOI: 10.1002/masy.201700019

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    その他リンク: http://orcid.org/0000-0002-9494-3004

  • Rheo-Raman Spectroscopic Study of Microscopic Deformation Behavior for Ultra Low-Density Polyethylene (ULDPE) 査読

    Takumitsu Kida, Yusuke Hiejima, Koh-hei Nitta

    Polymer International   2018年1月

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    出版者・発行元:Wiley-Blackwell  

    DOI: 10.1002/pi.5533

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  • Effect of Strain Rate on Microscopic Deformation Behavior of High-density Polyethylene under Uniaxial Stretching 査読

    Takumitsu Kida, Yusuke Hiejima, Koh-Hei Nitta

    MATEC Web of Conferences   130   2017年10月

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    記述言語:英語   掲載種別:研究論文(国際会議プロシーディングス)   出版者・発行元:EDP Sciences  

    The microscopic deformation behaviors such as the load sharing and the molecular orientation of high-density polyethylene under uniaxial stretching at various strain rates were investigated by using in-situ Raman spectroscopy. The chains within crystalline phase began to orient toward the stretching direction beyond the yielding region and the orientation behavior was not affected by the strain rate. While the stretching stress along the crystalline chains was also not affected by the strain rate, the peak shifts of the Raman bands at 1130, 1418, 1440 and 1460 cm-1, which are sensitive to the interchain interactions obviously, depended on the strain rate
    the higher strain rates lead to the stronger stretching stress or negative pressure on the crystalline and amorphous chains. These effects of the strain rate on the microscopic deformation was associated with the cavitation and the void formation leading to the release of the internal pressure.

    DOI: 10.1051/matecconf/201713005001

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    その他リンク: http://orcid.org/0000-0002-9494-3004

  • The evaluation of degradation mechanism of polyolefins, and development of non-destructive evaluating method 査読

    Igarashi T, Hiejima Y, Kida T, Nitta K.-H, Yonezawa Y

    Annual Technical Conference - ANTEC, Conference Proceedings   2017-May   1207 - 1211   2017年

  • Molecular orientation behavior of isotactic polypropylene under uniaxial stretching by rheo-Raman spectroscopy 査読

    T. Kida, Y. Hiejima, K. -H. Nitta

    EXPRESS POLYMER LETTERS   10 ( 8 )   701 - 709   2016年8月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:BUDAPEST UNIV TECHNOL & ECON  

    The molecular orientation behavior of isotactic polypropylene (iPP) is investigated by using in situ Raman spectroscopy under tensile tests. A versatile method of the tilt-angle correction for the orientation parameters is newly developed, where the molecular orientation in highly oriented specimens is assumed to be entropically favorable. The real-time changes of orientation parameters and orientation distribution functions are determined for the molecular chain axis of iPP during uniaxial stretching. The molecular orientation remains random in the elastic region, and increases after the first yield point. In the yielding region, a broad distribution of orientation toward an intermediate angle of 30-70 degrees from the stretching direction is observed. This is interpreted as reorientation of the crystalline chains being hindered by rigid, bulky lamellar cluster units. After the yielding region, orientation toward the stretching direction proceeds rapidly, approaching highly oriented states.

    DOI: 10.3144/expresspolymlett.2016.63

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    その他リンク: http://orcid.org/0000-0002-9494-3004

  • Raman spectroscopic study of high-density polyethylene during tensile deformation 査読

    Takumitsu Kida, Yusuke Hiejima, Koh-hei Nitta

    International Journal of Experimental Spectroscopic Techniques   1 ( 1 )   1   2016年1月

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    担当区分:筆頭著者   記述言語:英語   掲載種別:研究論文(学術雑誌)  

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  • Rheo-optical Raman study of microscopic deformation in high-density polyethylene under hot drawing 査読

    Takumitsu Kida, Yusuke Hiejima, Koh-Hei Nitta

    POLYMER TESTING   44   30 - 36   2015年7月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCI LTD  

    In situ observation of the microscopic structural changes in high-density polyethylene during hot drawing was performed by incorporating a temperature-controlled tensile machine into a Raman spectroscopy apparatus. It was found that the load sharing and molecular orientation during elongation drastically changed at 50 degrees C. The microscopic stress of the crystalline chains decreased with increasing temperature and diminished around 50 degrees C. Moreover, the orientation of the crystalline chains was greatly promoted above 50 degrees C. These microscopic structural changes were caused by the thermal activation of the molecular motion within lamellar crystalline chains owing to the onset of relaxation of the crystalline phase. (C) 2015 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.polymertesting.2015.03.018

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    その他リンク: http://orcid.org/0000-0002-9494-3004

  • Deformation mechanism of high-density polyethylene probed by in situ Raman spectroscopy 査読

    Takumitsu Kida, Tatsuya Oku, Yusuke Hiejima, Koh-hei Nitta

    POLYMER   58   88 - 95   2015年2月

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    記述言語:英語   掲載種別:研究論文(学術雑誌)   出版者・発行元:ELSEVIER SCI LTD  

    The microscopic mechanism of high-density polyethylene under uniaxial drawing is investigated using in situ Raman spectroscopy. From the peak shifts of the symmetric and anti-symmetric C-C stretching modes, it is found that the load sharing on the polymer chain in the yielding region is anisotropic with stretching along the chain and compression perpendicular to the chain. The orientation functions (&lt; P2 &gt; and &lt; P4 &gt;) as well as the orientation distribution function (N(theta)) are determined from the polarized Raman spectra. The molecular orientation with cold drawing is found to proceed more effectively for lower crystallinity specimens. In the yielding region, it is also found that N(theta) has a maximum at the polar angle theta = 30-70 degrees. This peculiar behavior in the microscopic scale is explained by the preferential collapse of spherulites and the existence of lamellar clusters as the bulky mobile units. (C) 2014 Elsevier Ltd. All rights reserved.

    DOI: 10.1016/j.polymer.2014.12.030

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    その他リンク: http://orcid.org/0000-0002-9494-3004

  • Rheo-Raman Spectroscopic Study of Uniaxial Plastic Deformation Behavior in High-Density Polyethylene Solids 査読

    Yusuke Hiejima, Takumitsu Kida, Koh-hei Nitta

    Advances in Materials Science Research. Volume 20   2015年

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  • ラマン分光から見た高密度ポリエチレンの構造変化

    比江嶋祐介, 木田拓充, 新田晃平

    次世代ポリオレフィン総合研究   8   77   2014年11月

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  • 放射光X線を用いたポリエチレン配向フィルムの延伸過程で生じる構造変化の解析 招待 査読

    木田拓充

    マテリアルライフ学会誌   35 ( 3 )   2023年12月

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    担当区分:筆頭著者, 責任著者   記述言語:日本語   掲載種別:記事・総説・解説・論説等(学術雑誌)  

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  • ラマン分光法を用いた結晶性高分子の構造解析手法

    木田拓充

    光アライアンス   34 ( 1 )   18 - 22   2023年1月

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    担当区分:筆頭著者, 責任著者   記述言語:日本語   掲載種別:記事・総説・解説・論説等(商業誌、新聞、ウェブメディア)  

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  • ラマン分光法を用いた結晶性高分子の構造解析手法 招待

    木田拓充

    光アライアンス   34 ( 1 )   18 - 22   2023年1月

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    記述言語:日本語   掲載種別:記事・総説・解説・論説等(商業誌、新聞、ウェブメディア)   出版者・発行元:日本工業出版   参加形態:共同(主担当)  

  • 分子量分布を利用した物性制御技術 招待

    木田拓充

    高分子   71 ( 12 )   621 - 622   2022年12月

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    担当区分:筆頭著者, 責任著者   記述言語:日本語  

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  • 分子量分布を利用した物性制御技術 招待

    木田拓充

    高分子   71 ( 12 )   621 - 622   2022年12月

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    記述言語:日本語   掲載種別:速報,短報,研究ノート等(学術雑誌)   出版者・発行元:高分子学会  

  • 結晶性高分子の力学物性とラマン分光法 招待

    木田拓充

    成形加工   33 ( 5 )   148 - 150   2021年5月

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    担当区分:筆頭著者, 責任著者   記述言語:日本語   掲載種別:記事・総説・解説・論説等(学術雑誌)  

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  • 結晶性高分子の力学物性とラマン分光法 招待

    木田拓充

    成形加工   33 ( 5 )   148 - 150   2021年5月

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    記述言語:日本語   掲載種別:速報,短報,研究ノート等(学術雑誌)   出版者・発行元:プラスチック成形加工学会  

  • 研究室紹介 名古屋大学 工学研究科 レオロジー物理工学研究室

    増渕 雄一, 土肥 侑也, 木田 拓充, 畝山 多加志

    49 ( 1 )   49 - 51   2021年2月

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    記述言語:日本語  

    DOI: 10.1678/rheology.49.49

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  • Synthesis and properties of block copolymers composed of norbornene/higher alpha-olefin gradient segments using ansa-fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)(4)] catalyst system (Nov, 10.1039/d0py01370f, 2021)

    Haobo Yuan, Takumitsu Kida, Ryo Tanaka, Zhengguo Cai, Yuushou Nakayama, Takeshi Shiono

    POLYMER CHEMISTRY   12 ( 5 )   771 - 771   2021年2月

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    記述言語:英語   出版者・発行元:ROYAL SOC CHEMISTRY  

    Correction for 'Synthesis and properties of block copolymers composed of norbornene/higher alpha-olefin gradient segments using ansa-fluorenylamidodimethyltitanium-[Ph3C][B(C6F5)(4)] catalyst system' by Haobo Yuan et al., Polym. Chem., 2021, DOI: ; 10.1039/d0py01370f.

    DOI: 10.1039/d1py90010b

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  • ラマン分光法を利用したポリオレフィン樹脂の構造・物性評価 招待

    比江嶋祐介, 木田拓充, 五十嵐敏郎, 新田晃平

    科学と工業   92 ( 5 )   120   2018年

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    記述言語:日本語   掲載種別:記事・総説・解説・論説等(商業誌、新聞、ウェブメディア)   出版者・発行元:大阪工研協会  

  • ラマン分光法を用いた高分子成形体の配向マッピングと劣化診断 招待

    比江嶋祐介, 木田拓充, 五十嵐敏郎, 新田晃平

    ケミカルエンジニヤリング   63 ( 3 )   14   2018年

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    記述言語:日本語   掲載種別:記事・総説・解説・論説等(商業誌、新聞、ウェブメディア)   出版者・発行元:化学工業  

  • ラマン分光法を利用したプラスチック材料の非破壊・非接触劣化診断 招待

    比江嶋祐介, 木田拓充, 五十嵐敏郎, 新田晃平

    コンバーテック   537   76   2017年

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    記述言語:日本語   掲載種別:記事・総説・解説・論説等(商業誌、新聞、ウェブメディア)   出版者・発行元:加工技術研究会  

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受賞

  • Rising Stars in Polymer Science 2023

    2023年11月   Polymer Journal  

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    受賞区分:学会誌・学術雑誌による顕彰 

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  • Excellent Poster Award

    2019年12月   The 8th Asian Polyolefin Workshop  

    木田拓充

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  • 金沢大学自然科学研究科長賞

    2019年3月   金沢大学  

    木田拓充

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    受賞国:日本国

  • Young Scientist Poster Award

    2018年12月   The 12th JSPS International Polymer Conference  

    木田拓充

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  • 若手優秀ポスター賞

    2018年11月   平成30年度繊維学会秋季研究発表会  

    木田拓充

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  • 若手優秀発表賞

    2016年6月   平成28年度繊維学会年次大会  

    木田拓充

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  • 優秀研究賞

    2015年11月   第64回高分子学会北陸支部研究発表会  

    木田拓充

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  • 優秀発表賞

    2015年7月   第9回北陸地区化学工学研究交流会  

    木田拓充

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    受賞区分:国内学会・会議・シンポジウム等の賞  受賞国:日本国

  • BestPresentation賞

    2014年5月   日本レオロジー学会第41年会  

    木田拓充

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  • 優秀ポスター賞

    2014年5月   第63回高分子学会年次大会  

    木田拓充

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    受賞区分:国内学会・会議・シンポジウム等の賞  受賞国:日本国

  • 金沢大学理工学域長賞

    2014年3月   金沢大学  

    木田拓充

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    受賞国:日本国

  • 優秀ポスター賞

    2013年9月   第61回レオロジー討論会  

    木田拓充

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共同研究・競争的資金等の研究課題

  • プラスチックの空間的不均一分解メカニズムの解明

    2023年11月 - 2024年10月

    住友財団  基礎科学研究助成 

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    担当区分:研究代表者 

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  • プラスチックの不均一分解の可視化技術開発と分解メカニズムの解明

    2023年10月 - 2027年3月

    国立研究開発法人 科学技術振興機構  さきがけ 

    木田拓充

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    担当区分:研究代表者 

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  • 特定分子量成分の直接観察による分子量分布と力学物性の関係解明への挑戦

    研究課題/領域番号:23K13798  2023年4月 - 2026年3月

    日本学術振興会  科学研究費助成事業 若手研究  若手研究

    木田 拓充

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    担当区分:研究代表者 

    配分額:4680000円 ( 直接経費:3600000円 、 間接経費:1080000円 )

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  • 分子量分布制御による高機能性プラスチックの開発

    2022年7月 - 2023年3月

    公益財団法人 三谷研究開発支援財団  2022年度研究助成 

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    担当区分:研究代表者 

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  • 重水素化プローブ分子鎖の直接観察による高分子材料の結晶化機構に与える分子量分布の影響の解明

    2022年4月 - 2024年3月

    公益財団法人 小笠原敏晶記念財団  一般研究助成 

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    担当区分:研究代表者 

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  • 分子分光法を用いた延伸過程における重水素化分子鎖の直接観察による分子量分布と力学物性の関係解明への挑戦

    2022年4月 - 2023年3月

    公益財団法人 池谷科学技術振興財団  単年度研究助成 

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    担当区分:研究代表者 

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  • 振動分光法を用いた重水素化プローブ分子鎖の直接観察による高分子の変形メカニズムの解明

    2021年11月 - 2022年11月

    澁谷学術文化スポーツ振興財団  大学の新技術・研究活動への奨励金 

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    担当区分:研究代表者 

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  • 構造不均一性の導入による高強度・高延伸性熱可塑性エラストマーの開発

    2021年10月 - 2023年3月

    公益財団法人 服部報公会  令和3年度工学研究奨励援助金 

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    担当区分:研究代表者 

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  • 高機能・高性能環状オレフィンコポリマーの開発

    2021年7月 - 2022年3月

    令和3年度研究拠点形成支援事業 萌芽的研究支援 

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    担当区分:研究代表者 

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  • 重水素化ラベル法を用いた分子量が高分子の構造形成に与える影響の解明

    2021年4月 - 2022年3月

    公益財団法人 日本科学協会  笹川科学研究助成 

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    担当区分:研究代表者 

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  • 結晶性高分子のひずみ硬化挙動に対する新規分子論モデルの提唱

    研究課題/領域番号:20K15345  2020年4月 - 2022年3月

    日本学術振興会  科学研究費助成事業 若手研究  若手研究

    木田 拓充

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    配分額:4160000円 ( 直接経費:3200000円 、 間接経費:960000円 )

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  • 分子量分布を利用した高機能プラスチックの開発

    2019年4月 - 現在

    科学研究費補助金 

  • 高分子の合成と物性技術の連携による分子量分布の物性に対する本質的役割の解明

    2019年4月 - 2022年3月

    特別研究員奨励費(PD) 

    木田拓充

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    配分額:52000000円 ( 直接経費:4000000円 、 間接経費:48000000円 )

  • 偏光ラマン分光法を用いた結晶性高分子材料の3次元配向評価

    2016年4月 - 2019年3月

    特別研究員奨励費(DC1) 

    木田拓充

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    配分額:2800000円 ( 直接経費:2800000円 )

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講演・口頭発表等

  • 分子量分布を利用した結晶性高分子の物性改善手法 招待

    木田拓充

    第188回答会高分子研究会講演会  2023年12月 

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    開催年月日: 2023年12月

    記述言語:日本語   会議種別:口頭発表(招待・特別)  

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  • Rheo-Raman分光法を用いた結晶性高分子における流動結晶化の分子量依存性の評価

    木田拓充, 上西尚輝, 竹下宏樹, 徳満勝久

    プラスチック成形加工学会 第31回秋季大会  2023年11月 

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    開催年月日: 2023年11月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Mechanical Properties and Morphology of Polyethylene Films Processed by Extruder with Molten Resin Reservoir

    Takumitsu Kida, Kazuki Imai, Hiroki Takeshita, Katsuhisa Tokumitsu, Kazunari Kimura, Kenji Ebara

    International Symposium on Feedstock Recycling of Polymeric Materials  2023年11月 

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    開催年月日: 2023年11月

    記述言語:英語   会議種別:ポスター発表  

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  • 結晶性高分子のスクラッチ挙動に与える高次構造の影響 〜引張試験との比較検討〜 招待

    木田拓充

    日本スクラッチコンソーシアム 第27回会議  2023年10月 

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    開催年月日: 2023年10月

    記述言語:日本語   会議種別:口頭発表(招待・特別)  

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  • ポリエチレンの溶融加工時における樹脂溜まり効果

    木田拓充

    プラスチック成形加工学会 環境・リサイクル委員会主催講演会  2023年10月 

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    開催年月日: 2023年10月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Rheo-Raman分光法を用いたポリエチレンの流動結晶化挙動に与える分子量の影響の評価

    木田拓充, 上西尚輝, 竹下宏樹, 山口政之, 徳満勝久

    第71回レオロジー討論会  2023年10月 

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    開催年月日: 2023年10月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • ラマン分光法を用いた短鎖分岐構造がポリエチレンの構造と物性に与える影響の解明

    木田拓充, 田中亮, 塩野毅, 竹下宏樹, 徳満勝久

    第72回高分子討論会  2023年9月 

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    開催年月日: 2023年9月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 短鎖分岐構造の導入がポリエチレンの固体力学物性に与える影響

    木田拓充, 田中亮, 塩野毅, 徳満勝久

    第17回次世代ポリオレフィン総合研究会  2023年8月 

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    開催年月日: 2023年8月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Direct Observation of Role of Each Molecular Weight Component on Tensile Properties of Polyethylene Solids 招待

    Takumitsu Kida

    9th International Discussion Meeting on Relaxations in Complex Systems  2023年8月 

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    開催年月日: 2023年8月

    記述言語:英語   会議種別:口頭発表(招待・特別)  

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  • Microscopic Deformation Behavior of Polyethylene Solids with Different Molecular Weight Distributions using Rheo-Raman Spectroscopy

    Takumitsu Kida, Ryo Tanaka, Takeshi Shiono, Masayuki Yamaguchi

    13th International Polymer Conference  2023年7月 

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    開催年月日: 2023年7月

    記述言語:英語   会議種別:口頭発表(一般)  

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  • Rheo-Raman分光法を用いた重水素化分子鎖の直接観察によるポリエチレンの一軸変形挙動の解析

    木田拓充, 田中亮, 塩野毅, 山口政之

    プラスチック成形加工学会 第34回年次大会  2023年6月 

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    開催年月日: 2023年6月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Influences of Shape of Molecular Weight Distribution on Tensile Properties of Polyethylene Solids

    Takumitsu Kida, Ryo Tanaka, Takeshi Shiono, Masayuki Yamaguchi, Katsuhisa Tokumitsu

    8th Pacific Rim Conference on Rheology  2023年5月 

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    開催年月日: 2023年5月

    記述言語:英語   会議種別:口頭発表(一般)  

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  • 結晶性高分子の一軸延伸過程における不均一構造変化の直接観察 招待

    木田拓充

    日本レオロジー学会 第50回記念年会  2023年5月 

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    開催年月日: 2023年5月

    記述言語:日本語   会議種別:口頭発表(招待・特別)  

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  • Rheo-Raman Spectroscopic Study of Flow-Induced Crystallization of Polyethylene

    Takumitsu Kida, Khunanya Janchai, Masayuki Yamaguchi

    ANTEC2023  2023年3月 

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    開催年月日: 2023年3月

    記述言語:英語   会議種別:口頭発表(一般)  

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  • Raman Spectroscopic Study of Microscopic Deformation Behavior of Semi-Crystalline Polymeric Solids 招待

    Takumitsu Kida

    2023 Trilateral Conference on Modern Challenges in Polymer Science and Technology  2023年1月 

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    開催年月日: 2023年1月

    記述言語:英語   会議種別:口頭発表(招待・特別)  

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  • 結晶性高分子固体におけるひずみ硬化挙動の構造論的解析

    木田拓充, 比江嶋祐介, 新田晃平, 山口政之

    プラスチック成形加工学会 第30回秋季大会  2022年11月 

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    開催年月日: 2022年11月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 重水素化プローブ法を用いたポリエチレンの分子量分布と一軸引張り挙動の関係解明

    木田拓充, 田中亮, 塩野毅, 山口政之

    第70回レオロジー討論会  2022年10月 

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    開催年月日: 2022年10月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Rheo-Raman Spectroscopic Study of Flow-Induced Crystallization of Semi-Crystalline Polymers

    Takumitsu Kida, Khunanya Janchai, Masayuki Yamaguchi

    Asian Workshop on Polymer Processing 2022  2022年10月 

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    開催年月日: 2022年10月

    記述言語:英語   会議種別:口頭発表(一般)  

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  • Rheo-Raman分光測定を用いたポリエチレンの流動結晶化過程のその場観察

    木田拓充, ジャンチャイクナンヤ, 山口政之

    第71回高分子討論会  2022年9月 

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    開催年月日: 2022年9月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 分子量分布の形状が高密度ポリエチレンの一軸引張り挙動に与える影響の解明

    木田拓充, 田中亮, 塩野毅, 山口政之

    プラスチック成形加工学会 第33回年次大会  2022年6月 

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    開催年月日: 2022年6月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 重水素化プローブ分子鎖の直接観察による結晶性高分子の分子量分布と引張り挙動の関係解明

    木田拓充, 田中亮, 塩野毅, 山口政之

    第71回高分子学会年次大会  2022年5月 

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    開催年月日: 2022年5月

    記述言語:日本語   会議種別:ポスター発表  

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  • ラマン分光法を用いた重水素化プローブ分子鎖の直接観察によるポリエチレンの一軸引張り挙動の解明

    木田拓充, 田中亮, 塩野毅, 山口政之

    日本レオロジー学会 第49年会  2022年5月 

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    開催年月日: 2022年5月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Raman Spectroscopic Study of Microscopic Deformation Behavior of Semi-Crystalline Polymeric Materials under Uniaxial Stretching 招待

    Takumitsu Kida

    13th Annual Conference on Polymer Science and Engineering  2022年4月 

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    開催年月日: 2022年4月

    記述言語:英語   会議種別:口頭発表(基調)  

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  • Morphology, Crystallization Behavior, and Mechanical Properties of Polypropylene Containing Ultra-High-Molecular-Weight Component

    Takumitsu Kida, Takeyoshi Kimura, Ayaka Eno, Khunanya Janchai, Masayuki Yamaguchi, Yasuhiko Otsuki, Tokutaro Kimura, Tomoaki Mizukawa, Tomoya Murakami, Kazuki Hato, Tomoya Okawa

    37th International Conference of the Polymer Processing Society  2022年4月 

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    開催年月日: 2022年4月

    記述言語:英語   会議種別:口頭発表(一般)  

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  • 短鎖分岐構造がポリエチレンの構造と物性に与える影響の解明

    木田拓充, 田中亮, 塩野毅, 山口政之

    プラスチック成形加工学会 第29回秋季大会  2021年11月 

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    開催年月日: 2021年11月 - 2021年12月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 分岐分率が直鎖状低密度ポリエチレンの構造と力学物性に与える影響

    木田拓充, 田中亮, 塩野毅, 山口政之

    第69回レオロジー討論会  2021年10月 

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    開催年月日: 2021年10月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Raman Spectroscopic Analysis of Plastic Deformation of Semi-Crystalline Polymeric Solids under Uniaxial Stretching 招待

    Takumitsu Kida

    2nd Global Webinar on Mechanical and Mechanics Engineering  2021年9月 

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    開催年月日: 2021年9月

    記述言語:英語   会議種別:口頭発表(基調)  

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  • 単分散ポリエチレンの分子量が一軸延伸挙動に与える影響の評価

    木田拓充, 田中亮, 塩野毅, 比江嶋祐介, 新田晃平

    プラスチック成形加工学会 第32回年次大会  2021年6月 

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    開催年月日: 2021年6月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 分子量分布の形状の違いがポリエチレンの一軸引張挙動に与える影響

    木田拓充, 田中亮, 比江嶋祐介, 新田晃平, 塩野毅

    第70回高分子学会年次大会  2021年5月 

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    開催年月日: 2021年5月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 分子量分布の形状がポリエチレンの一軸引張挙動に与える影響

    木田拓充, 田中亮, 塩野毅, 比江嶋祐介, 新田晃平

    日本レオロジー学会 第48年会  2021年5月 

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    開催年月日: 2021年5月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • ポリエチレンの分子量が構造と物性の関係に与える影響

    木田拓充, 田中亮, 塩野毅, 比江嶋祐介, 新田晃平

    日本レオロジー学会 第48年会  2021年5月 

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    開催年月日: 2021年5月

    記述言語:日本語   会議種別:ポスター発表  

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  • Influences of Shape of Molecular Weight Distribution on Tensile Properties of Polyethylene Solids

    Takumitsu Kida, Ryo Tanaka, Yusuke Hiejima, Koh-hei Nitta, Takeshi Shiono

    21st International Union of Materials Research Societies International Conference in Asia  2021年2月 

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    開催年月日: 2021年2月

    記述言語:英語   会議種別:口頭発表(一般)  

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  • ラマン分光法を用いた分子量分布が異なるポリエチレンの一軸変形挙動の解析

    木田拓充, 塩野毅, 比江嶋祐介, 新田晃平

    プラスチック成形加工学会 第28回秋季大会  2020年12月 

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    開催年月日: 2020年12月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 単分散ポリエチレンにおける分子量が物性に与える影響の解明

    木田拓充, 田中亮, 塩野毅, 比江嶋祐介, 新田晃平

    第68回レオロジー討論会  2020年10月 

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    開催年月日: 2020年10月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 分子量分布の形状がポリエチレンの構造と物性に与える影響

    木田拓充, 田中亮, 比江嶋祐介, 新田晃平, 塩野毅

    第69回高分子討論会  2020年9月 

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    開催年月日: 2020年9月

    記述言語:日本語   会議種別:ポスター発表  

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  • 分子量分布の形状が異なるポリエチレンにおける構造と物性の関係

    木田拓充, 田中亮, 比江嶋祐介, 新田晃平, 塩野毅

    第69会高分子学会年次大会  2020年5月 

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    開催年月日: 2020年5月

    記述言語:日本語   会議種別:ポスター発表  

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  • Rheo-Raman分光法を用いた熱可塑性ポリアミドエラストマーの一軸変形挙動の解析

    木田拓充, 佐々木泰生, 比江嶋祐介, 前田修一, 新田晃平

    日本レオロジー学会 第47年会  2020年5月 

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    開催年月日: 2020年5月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • ポリエチレンの力学物性と高次構造に対する分子量分布の影響

    木田拓充, 田中亮, 塩野毅, 比江嶋祐介, 新田晃平

    日本レオロジー学会 第47年会  2020年5月 

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    開催年月日: 2020年5月

    記述言語:日本語   会議種別:ポスター発表  

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  • 分子量及び分子量分布が結晶性高分子材料の構造と物性に与える影響

    木田拓充

    2019年度 不規則系物質先端科学研究会  2020年2月 

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    開催年月日: 2020年2月

    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Rheo-Raman分光法を用いた結晶性高分子の結晶化・変形挙動の評価 招待

    木田拓充

    高分子加工技術研究会 第96回例会  2023年3月 

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    記述言語:日本語   会議種別:口頭発表(招待・特別)  

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  • 振動分光法を用いた結晶性高分子の変形過程における構造変化の直接観察 招待

    木田拓充

    2021年度 繊維学会東北・北海道支部講演会  2022年1月 

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    記述言語:日本語   会議種別:口頭発表(招待・特別)  

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  • In Situ Raman Spectroscopic Study of Microscopic Deformation Behaviors of Poly(ether-block-amide) Thermoplastic Elastomers under Uniaxial Stretching

    Takumitsu Kida, Taisei Sasaki, Yusuke Hiejima, Shuichi Maeda, Koh-hei Nitta

    Pacifichem 2021  2021年12月 

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    記述言語:英語   会議種別:口頭発表(一般)  

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  • 分子量分布および分岐構造がポリエチレンの一軸引張挙動に与える影響の解析

    木田拓充

    第15回次世代ポリオレフィン総合研究会  2021年8月 

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    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Influences of Molecular Weight Distribution on Morphology and Mechanical Properties of Polyethylene Solids 国際会議

    木田拓充

    The 8th Asian Polyolefin Workshop (APO2019)  2019年12月 

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    記述言語:英語   会議種別:ポスター発表  

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  • 分子量および分子量分布が結晶性高分子固体の構造と物性に与える影響 招待

    木田拓充

    関西レオロジー研究会 第77回例会  2019年11月 

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    記述言語:日本語   会議種別:口頭発表(招待・特別)  

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  • Rheo-Raman分光法を用いた高密度ポリエチレンの一軸延伸過程における微視的変形挙動の観察

    木田拓充

    第29回日本MRS年次大会  2019年11月 

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    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 結晶性高分子固体におけるひずみ硬化現象の構造論的解釈

    木田拓充

    第27回成形加工シンポジア'19  2019年11月 

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    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 分子量分布が高密度ポリエチレンの構造と物性に与える影響

    木田拓充

    第67回レオロジー討論会  2019年10月 

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    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Rheo-Raman分光法を用いた高密度ポリエチレンの一軸延伸過程における微視的変形挙動の観察

    木田拓充

    第68回高分子討論会  2019年9月 

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    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 分子量分布がポリエチレンの構造と物性に与える影響

    木田拓充

    第14回次世代ポリオレフィン総合研究会  2019年8月 

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    記述言語:日本語   会議種別:口頭発表(一般)  

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  • 赤外・ラマン分光法を用いた高分子材料の構造解析 招待

    木田拓充

    2019年8月 

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    記述言語:日本語   会議種別:公開講演,セミナー,チュートリアル,講習,講義等  

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  • 分子量分布が高密度ポリエチレンの一軸延伸挙動に与える影響

    木田拓充

    日本レオロジー学会 第45年会  2019年5月 

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    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Rheo-Raman spectroscopic studies of the influence of α relaxation process on microscopic deformation behaviors of high-density polyethylene 国際会議

    木田拓充

    The 12th SPSJ International Polymer Conference  2018年12月 

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    記述言語:英語   会議種別:口頭発表(一般)  

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  • Rheo-Raman Spectroscopic Studies of Microscopic Deformation Behaviors under Uniaxial Stretching of High-Density Polyethylene Solids 国際会議

    木田拓充

    The 12th SPSJ International Polymer Conference  2018年12月 

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    記述言語:英語   会議種別:ポスター発表  

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  • 分子量分布が異なる高密度ポリエチレンの一軸延伸過程における微視的変形挙動の解明

    木田拓充

    平成30年度繊維学会秋季研究発表会  2018年11月 

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    記述言語:日本語   会議種別:ポスター発表  

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  • In-Situ Raman Studies of Deformation Mechanism of Polyethylene Solids under Elongation 国際会議

    木田拓充

    Japan-Indonesia International Scientific Conference 2018  2018年10月 

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    記述言語:英語   会議種別:口頭発表(一般)  

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  • Rheo-Optical Raman Studies of Microscopic Deformation Behaviors of Polyethylene Solids with Various Molecular Weight Distribution under Unaixial Stretching 国際会議

    木田拓充

    7th International Conference on Polyolefin Characterization  2018年10月 

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    記述言語:英語   会議種別:ポスター発表  

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  • In-situラマン分光法を用いたポリエチレンの熱延伸過程における微視的変形挙動の解明

    木田拓充

    第67回高分子討論会  2018年9月 

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    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Rheo-Raman分光法を用いた分子量が異なるポリエチレンの延伸過程における微視的変形挙動の解析

    木田拓充

    プラスチック成形加工学会 第29回年次大会  2018年6月 

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    記述言語:日本語   会議種別:口頭発表(一般)  

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  • Rheo-Raman Study of the Microscopic Deformation Behavior of High-density Polyethylene with Various Molecular Weight Distribution 国際会議

    木田拓充

    The 7th Pacific Rim Conference on Rheology  2018年6月 

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    記述言語:英語   会議種別:口頭発表(一般)  

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  • ラマン分光法を用いた分子量分布の異なる高密度ポリエチレンの一軸延伸過程における微視的変形挙動の解析

    木田拓充

    第67回高分子学会年次大会  2018年5月 

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    記述言語:日本語   会議種別:ポスター発表  

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  • Rheo-Raman分光法を用いたポリエチレンの微視的変形挙動の解析

    木田拓充

    日本レオロジー学会 第45年会  2018年5月 

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    記述言語:日本語   会議種別:口頭発表(一般)  

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▼全件表示

担当経験のある科目(授業)

  • 人間探求学(材料科学)

    2023年4月 - 現在 機関名:滋賀県立大学

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    科目区分:学部専門科目 

  • 材料科学実験Ⅰ

    2023年4月 - 現在 機関名:滋賀県立大学

     詳細を見る

    科目区分:学部専門科目 

  • 高分子化学特論Ⅱ

    機関名:北陸先端科学技術大学院大学